The control and manipulation of light beams at the nanoscale is one of the main requirements for many advanced applications in free-space and integrated photonics and quantum optics, as for example for the development of single-photon sources and coherent nanosources (nanolasers). Consequently, the design and fabrication of novel nanostructured materials able to satisfy this demand has become one of the greatest challenges for nanophotonics.
Some of the investigated topics:
* Single-photon emitters
* Nanolasers
* Emitter-Nanostructures interaction for controlling the emission quantum efficiency
* Energy transfer processes between emitters and plasmonic nanostructures
Metamaterials (MMs) are artificially nanostructured materials whose optical functionalities go beyond ("meta") those of their elementary constituents, and which can be engineered by properly controlling the properties and the coupling of the functional nanometric building-blocks on a sub-wavelength scale. At NSG we investigate:
* MMs with hyperbolic optical dispersion
* Epsilon-Near Zero (ENZ) MMs
* Time-varying MMs
When photons in the visible or near-infrared range interact with metallic nanostructures whose size, shape and composition (e.g., Au or Ag or their alloys) suitably designed to exploit the surface plasmon resonance phenomenon, it becomes possible to localize the electromagnetic field intensity in sub-wavelength regions (surpassing the diffraction limit) or to exploit peculiar phenomena working at the nanoscale such as the extraordinary optical transmission from ordered arrays of n anohole with sub-wavelength diameter) in a thin plasmonic film. Some investigated topics:
* Linear and nonlinear optical properties of metal nanostructures
* Plasmonic bio-sensors
* Modeling of the plasmonic properties of isolated or interacting nanostructures
Photocatalysis is one of the most interesting processes for promoting chemical reactions due to its use of solar energy. The ability of plasmonic nanostructures to focus light and to locally amplify its intensity is extremely relevant when coupled to nanostructures of semiconducting oxides, allowing to control the injection of hot carriers activated during plasmonic resonances. Some investigated topics:
* High-surface area nanostructures of Co and Fe for electro-photocatalysis
* Photo-Catalysis
* Water remediation
The control of the surface properties in terms of hydrophobicity, conductivity or morphology allows the use of such chemically and/or morphologically patterned surfaces as an 'active' substrate to control dynamics of fluids above or more complex processes, like cell growth. Patterning can be achieved by (atmospheric) plasma or ion implantation. Some investigated topics:
* Thermodynamics of nucleation and growth
* Nano-alloying of immiscible elements by ion implantation
* Ion beam induced selective de-alloying
* Atmospheric Plasma treatments for chemical/morphological surface modification
* Nano- and Micro-patterned surfaces for cellular growth
The emission efficiency in the visible or near-infrared spectrum from quantum emitters can be improved by the coupling with suitably engineered Local Density of Optical States (LDOS) in plasmonic or dielectric metasurfaces.
Coherent and directional emission of light can be obtained by the virtual cavity effect produced by the resonant scattering of plasmonic metasurfaces coupled to dye emitters.
Spectral- and angle-dependent nonlinear optical (NLO) measurements are performed on hyperbolic metamaterials around their epsilon-near-zero (ENZ) frequency showing a tunability in nonlinear refraction and absorption.
The possibility to obtain single-photon sources in the visible range is investigated by studying the transition from classical to quantum regime in the photons emitted at room temperature by N-V centers in nanodiamonds.
Water and wastewater purification is one of the key issues of environmental safeguarding, as pesticides, dyes, and contaminants of emerging concerns frequently occur in natural water and wastewater, severely limiting water reuse.
Room temperature atmospheric pressure plasma jet (APPJ) treatments in reducing atmosphere is performed to enhance the photoluminescence (PL) properties of single crystal ZnO nanorods
NanoStructures Group (NSG)
Dept. of Physics and Astronomy,
via Marzolo 8, I-35131 Padova, ITALY
Easiest Website Builder